Dichroic Glass and other add on components
Many chemical compounds, such as cobalt, gold, silver, cadmium,
barium and lead can be added to the glass in order to achieve
clarity or an array of colors (Odorica). Some additives are toxic
and should not be used no matter how much they enhance the optical
quality of the glass.
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Aventurine and Dichroic are
relatively new types of glass.
Aventurine Glass
was discovered by chance,
hence its name (from the Italian word for chance, Avventura). The
sparkling effect of the Aventurine (Dei Rossi, above) is due to the
metal oxide incorporated in the glass (copper)
Dichroic Glass
is formed by electroplating various metal oxides on the glass
resulting in a spectrum of strikingly bright colors. Understanding
dichroism is problematic and requires some knowledge of physics and
optics. We are grateful for the help of the Physicist (and Glass Art
Connoisseur) Scott Bartky and that of the Artist – Physicist
Sherburne Slack.
The text that follows is a digest of their input.
Dichroic color
is not a pigment or a dye. Whereas the usual glass achieves its
color by absorbing all the colors you don't see, dichroic glass
achieves it through light waves loosely interfering with each other
while passing through ultra thin layers of metal oxides, vaporized
on the glass in a vacuum chamber.
These films of metal oxides represent the
multilayer
interference filter.
It is in this layer, over 100 times thinner than human hair, that
dichroism,
the property of exhibiting different colors by reflected or
transmitted light, occurs.
The result is a transparent, yet highly reflective colored surface.
The specific color is determined by the types of oxides, their
thicknesses and the viewing angle.
You can quickly determine if the glass is dichroic by tilting it and
seeing the color changes.
Although the
principles of
multilayer
interference filters
were known in the late 1800's, it wasn't until the 1920's and 1930's
that vacuum techniques advanced to the point where dichroic filters
could be fabricated in a laboratory setting. In WWII the need for
more and better optical instruments resulted in the development of
large industrial vacuum plating systems. Although these systems were
primarily used for mirrors and optical coatings, they were
nonetheless capable of depositing multi-layer films. In the late
1940's, the techniques of accurately and repeatable controlling the
thickness of very thin films were developed and large scale
production of dichroic filters became possible. They were used as
reflectors in film projection lamps. They were truly dichroic in
that they reflected the visible light towards the film and
transmitted the heat out the rear keeping it from burning the film.
In the last 50 years dichroic filters have found their way into
literally hundreds of applications ranging from eye-catching plastic
materials to measuring the makeup of atmospheres on Jupiter's moons.
The first artistic use of dichroic
glass was in Britain, in the 1960's. Its widespread use was in the
late 90's when the manufacturers of the filters began depositing
them on well known fully characterized artistic glass
Sherburne Slack’s sculpted letters
are very good examples of dichroism in glass art (above left).
Dichroic glass is a major component of Michael O’Keefe’s work (above
center)
A touch of dichroism enhances significantly Ray Howlett’s light
sculptures (above right).
Man did not create dichroism, Nature
did. Dichroic colors are the result of the same physical laws that
are responsible for the iridescent of opalescent crystal, the
butterfly wings, the scales of tropical fish and also the colors
produced by oil on water. The oil is spread so thin that the
thickness is on the order of the wavelength of light. Different
colors have different wavelengths. When the layer’s thickness is the
same as a particular color, that is the color transmitted through
the layer and the reflected one is a combination of the remaining
colors of the spectrum.